PENTE rules and hints:
Winning requires that the player achieve five of his/her pieces in a row or removal of five of the opponents pairs (or both in the same move), in any of eight directions including diagonals.
Pairs:
A pair is taken when a player makes a move that places his/her piece in such a way that the opponent's pair becomes blocked on both sides.  Only pairs can be taken from the board.

Pairs are not lost by moving into already blocked arrangements.
Triples:
Aside from being weary of loosing pairs, immediately defending against an "open three" by blocking either end avoids loosing 2 moves later.

An open three looks like .OOO. or .O.OO. in any direction. Watch for multi-directional open three's.
Good luck!